Fullerene-Indene Conjugation フラーレン誘導体 大量合成

Outline

J. Org. Chem., 2018, 83, pp 4348-4354.
Open Access DOI: 10.1021/acs.joc.7b03209

“Selective, Scalable Synthesis of C60-Fullerene/Indene Monoadducts Using a Microwave Flow Applicator”

Joshua P. Barham , Satoko Tanaka, Emiko Koyama, Noriyuki Ohneda, Tadashi Okamoto, Hiromichi Odajima, Jun-ichi Sugiyama, and Yasuo Norikane

Abstract
  The synergy of continuous processing and microwave heating technologies has unlocked scalable (g/h), safe and efficient reaction conditions for synthesis of fullerene/indene-based organic photovoltaic acceptor materials in a nonchlorinated solvent with levels of productivity unparalleled by previous syntheses. The microwave flow reactor sustains high temperature while employing short residence times, reaction conditions which uniquely allow the selective synthesis of fullerene/indene monoadducts. Design of experiments analysis revealed residence time as the most crucial factor for conversion and selectivity control.

Equipment information Reactor size: 200 mm, Maximum power: 250 W (SAIDA FDS INC.)

概要

(Update!!) 国立研究開発法人 産業技術総合研究所のプレスリリースより
「フロー型マイクロ波合成装置で有機材料の高効率合成が可能に」
-溶媒選択の幅を広げ、迅速な開発と柔軟な生産に貢献-
http://www.aist.go.jp/aist_j/press_release/pr2018/pr20180412/pr20180412.html
【研究者が語る!1分解説動画】

実験結果提供:産業技術総合研究所 Joshua Barham氏、小山恵美子先生、杉山順一先生、則包恭央先生
装置情報:200 mmキャビティ、250W

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